Ren-Zhong
Li
abc,
Gao-Lei
Hou
b,
Cheng-Wen
Liu
d,
Hong-Guang
Xu
b,
Xiang
Zhao
*c,
Yi Qin
Gao
*d and
Wei-Jun
Zheng
*b
aCollege of Electronics and Information, Xi'an Polytechnic University, Xi'an 710048, China
bBeijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. E-mail: zhengwj@iccas.ac.cn; Fax: +86 10 62563167; Tel: +86 10 62635054
cInstitute for Chemical Physics, School of Science, Xi'an Jiaotong University, Xi'an 710049, China. E-mail: xzhao@mail.xjtu.edu.cn
dBeijing National Laboratory for Molecular Sciences, Institute of Theoretical and Computational Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. E-mail: gaoyq@pku.edu.cn
First published on 18th November 2015
We investigated (NaI)2−(H2O)n (n = 0–6) clusters to examine the initial solvation process of (NaI)2 in water, using negative ion photoelectron spectroscopy and theoretical calculations. The structures of these clusters and their neutrals were determined by comparing ab initio calculations with experimental results. It is found that bare (NaI)2− is a L-shaped structure and the corresponding neutral is a rhombus. In (NaI)2−(H2O), the water molecule prefers to interact with the middle Na atom of the L-shaped (NaI)2−. For (NaI)2−(H2O)n clusters with n = 2–3, two types of structures are nearly degenerate in energy: one is L-shaped and the other is pyramid-shaped. As for (NaI)2−(H2O)n with n = 4–6, the dominant structures are pyramid-shaped. For the anionic clusters, one of the Na–I distances increases abruptly when n = 2; for the neutral clusters, rapid lengthening of the Na–I distances occurs when n = 4. Additionally, analyses of the reduced density gradient were carried out, and the results reveal that Na+–water interactions dominate in (NaI)2−(H2O)n for n ≤ 4, whereas I−–water and water–water interactions are significantly enhanced when n increases to 5.
As for the hydration of sodium iodide, the monomer has been investigated by many groups, because of its importance in photodissociation dynamics.21–24 Olleta et al. studied the structures, binding energies and electronic properties of NaI(H2O)1–6 based on ab initio calculations, and found that pentahydrated and hexahydrated clusters show dissociated structures.25 Peslherbe and co-workers23,24,26,27 investigated the structure, dynamics and stability of NaI–water systems using molecular dynamics simulations and found that the ion pair is quite stable with respect to dissociation into free ions, even in large clusters. Grégoire et al.28–30 studied NaI–(H2O)n and NaI–(NH3)n clusters by performing resonance-enhanced two-photon ionization experiments. Their results show a solvent-selective ionization behavior for sodium iodide clustered with various solvents. Raymond et al.31 studied the molecular structure and bonding of the surface of salt solutions of NaX (X: F, Cl, Br, I) using vibrational sum-frequency spectroscopy and the results indicated that the population of the anions at the uppermost layer of the surface diminished significantly. In addition, there also exists studies on the hydration of alkali-rich sodium iodide. Blades et al.32 studied the hydration energies of (MI)mM+ ions in the gas phase, where M+ = Na+, K+, Rb+, Cs+, with up to four water molecules, and their study showed that the sequential hydration bond energies for MIM(H2O)n+ and (MIm)M+ decrease with increasing n and m, respectively. Zhang et al.33 studied the dissolution processes of Na2I+ and Na3I2+ with the association of water molecules, and found that the separation of the Na–I ion pair for Na2I+ occurs when six H2O molecules are added to the salt cluster and only one or two H2O molecules are added to the salt cluster for Na3I2+. Only a limited number of studies on hydrated clusters containing more than one alkali halide unit have been conducted. Woon34 studied (LiF)2 and (LiF)2(H2O) based on MP2 calculations, and suggested that water causes a large distortion of the nearest LiF bond, with a change in (LiF)2(H2O) almost twice as large as that in LiF(H2O). Liu et al.35 studied (NaCl)3(H2O)n (n = 2–7) and found that a water molecule preferentially binds to the Na–Cl edge. Yamabe et al.16 studied the mechanism of ion separation of the NaCl microcrystal via the association of water with (NaCl)m. Fatemi and Bloomfield36 studied (NaI)nH2O− (n = 3, 4, 6) using photoelectron spectroscopy and found that the water molecule attaches to the edge of a NaI particle and orients itself to decrease the NaI particle's electron affinity.
In this work, in order to get a better understanding of how alkali halide clusters interact with water molecules, we conducted a combined experimental/theoretical study of the initial solvation process of (NaI)2 in water using negative ion photoelectron spectroscopy of (NaI)2−(H2O)n (n = 0–6) clusters and ab initio calculations.
Isomer | X′ | X | ||
---|---|---|---|---|
ADE (eV) | VDE (eV) | ADE (eV) | VDE (eV) | |
(NaI)2− | 1.56 ± 0.08 | 1.70 ± 0.08 | ||
(NaI)2−(H2O) | 1.03 ± 0.10 | 1.24 ± 0.10 | 1.46 ± 0.08 | 1.62 ± 0.08 |
(NaI)2−(H2O)2 | 0.83 ± 0.10 | 1.18 ± 0.10 | 1.37 ± 0.10 | 1.62 ± 0.08 |
(NaI)2−(H2O)3 | 0.74 ± 0.08 | 1.04 ± 0.10 | 1.37 ± 0.10 | 1.59 ± 0.08 |
(NaI)2−(H2O)4 | 0.75 ± 0.08 | 1.00 ± 0.08 | ||
(NaI)2−(H2O)5 | 0.79 ± 0.08 | 1.07 ± 0.08 | ||
(NaI)2−(H2O)6 | 0.84 ± 0.08 | 1.08 ± 0.08 |
The photoelectron spectrum of bare (NaI)2− at 532 nm shows an unresolved broad band feature centered at about 1.70 eV. The ADE of (NaI)2− is estimated to be 1.56 ± 0.08 eV. The spectrum shows a large change with a new band X′ showing up at the lower binding energy side when the first water molecule is adsorbed on (NaI)2−. The measured spectrum in the experiment shows that the major band feature X has a VDE of 1.62 eV and the weak new band X′ has a lower VDE of 1.24 eV. Similar to (NaI)2−(H2O), the double-peak spectral pattern in the threshold region is also observed in the spectra of (NaI)2−(H2O)n (n = 2–3), except that the peaks shift to a lower binding energy and the relative intensities of the X′ versus X band increases when n increases from 1 to 3. The peaks (X′ and X) of (NaI)2−(H2O)2 are centered at ∼1.18 and 1.62 eV, respectively, and those of (NaI)2−(H2O)3 are centered at ∼1.04 and 1.59 eV, respectively. These observations indicate that two kinds of isomers may coexist in the spectra of (NaI)2−(H2O)n (n = 1–3), corresponding to the X′ and X spectral features. The photoelectron spectra of (NaI)2−(H2O)n with n = 4–6 each has only a major broad feature X′, and the band X at the higher binding energy side disappears, suggesting that there is only one kind of dominant structure. The VDE of (NaI)2−(H2O)4 is measured to be about 1.00 eV; those of (NaI)2−(H2O)5 and (NaI)2−(H2O)6 shift to higher electron binding energies of 1.07 and 1.08 eV, respectively.
The changes of VDEs with the number of water molecules in the (NaI)2−(H2O)n (n = 0–6) clusters are shown in Fig. 2. It can be seen that the VDE of X of (NaI)2−(H2O)n first decreases when n changes from 0 to 1, stays nearly unchanged from 1 to 2, and then decreases again as n increases to 3. As for the VDE of X′ of (NaI)2−(H2O)n, the value first decreases when n changes from 1 to 4, and then increases when n increases from 4 to 6. These observations suggest that the Na–water interactions are very strong for (NaI)2−(H2O)n from n = 0 to 4, and the I−–water and water–water interactions are dominant when the fifth and sixth water molecules are adsorbed, as it has been analyzed previously that the alkali metal–water interactions reduce VDEs while anion–water and water–water interactions increase VDEs.42 These inferences will be confirmed by the analysis of interactions in Section 4.
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Fig. 5 Optimized geometries of the low-lying isomers of the neutral (NaI)2(H2O)n (n = 0–3) clusters. |
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Fig. 6 Optimized geometries of the low-lying isomers of the neutral (NaI)2(H2O)n (n = 4–6) clusters. |
Isomer | ΔEa (eV) | Sym. | State | Theo. | Expt. | ||
---|---|---|---|---|---|---|---|
VDE (eV) | VDE (eV) | ||||||
LC-ωPBE | CCSD(T) | ||||||
a The ΔE values are from the LC-ωPBE functional. | |||||||
(NaI)2− | 0A | 0.00 | C s | 2A | 1.83 | 1.62 | 1.70 |
0B | 0.27 | C 2v | 2A1 | 0.80 | 0.62 | ||
(NaI)2−(H2O) | 1A | 0.00 | C 1 | 2A | 1.77 | 1.58 | 1.62 |
1B | 0.19 | C 1 | 2A | 1.55 | 1.37 | 1.24 | |
(NaI)2−(H2O)2 | 2A | 0.00 | C s | 2A | 1.85 | 1.65 | 1.62 |
2B | 0.02 | C 2 | 2A | 1.56 | 1.39 | 1.18 | |
2C | 0.05 | C 1 | 2A | 1.30 | 1.13 | ||
(NaI)2−(H2O)3 | 3A | 0.00 | C 1 | 2A | 1.70 | 1.50 | 1.59 |
3B | 0.01 | C 1 | 2A | 1.16 | 1.04 | 1.04 | |
3C | 0.04 | C 1 | 2A | 1.26 | 1.10 | ||
(NaI)2−(H2O)4 | 4A | 0.00 | C s | 2A | 1.28 | 1.16 | 1.00 |
4B | 0.08 | C s | 2A | 1.19 | 1.07 | ||
(NaI)2−(H2O)5 | 5A | 0.00 | C 1 | 2A | 1.29 | 1.07 | |
5B | 0.05 | C 1 | 2A | 1.08 | |||
(NaI)2−(H2O)6 | 6A | 0.00 | C 1 | 2A | 1.25 | 1.08 | |
6B | 0.02 | C 1 | 2A | 1.08 |
Our calculations show that the global minimum of (NaI)2− is 0A in the 2A state with a L-shaped structure and Cs symmetry, and the angle ∠Na–I–Na is 122.5°. The theoretical VDE of (NaI)2− is 1.62 eV with the CCSD(T) method, close to the experimental value of 1.70 eV measured in this work. Isomer 0B is higher than 0A by 0.27 eV and it is a ring structure with C2v symmetry and a 2A1 state. The calculated VDE of 0B is 0.62 eV, which largely deviates from the experimental measurement. Therefore, we conclude that the L-shaped structure makes a main contribution to the photoelectron spectrum. For the (NaI)2 neutral, the most stable structure 0A′ is a rhombus with C2v symmetry, different from the square structure suggested by previous theoretical calculations.53 The significant deformations between the most stable structures of (NaI)2− and the corresponding neutral one indicate that the excess electron induces a significant change to the (NaI)2 framework.
We can see that the typical minimal energy structures of (NaI)2−(H2O) are formed by attaching a water molecule to the L-shaped (NaI)2−. In the most stable structure 1A, the water molecule interacts with the nearest Na1–I1 unit with its oxygen atom connecting to the middle Na atom (Na1) and with one H atom pointing to the terminal I atom (I1), and the Na1–I1 distance is longer than that in bare (NaI)2− by 0.12 Å. The theoretical VDE of 1.77 eV is in agreement with the experimental VDE (1.62 eV) of the second peak (X) in the photoelectron spectrum of (NaI)2−(H2O). In isomer 1A, the Na1–O bond length of 2.32 Å is shorter than the I1–H length of 2.72 Å, indicating that the Na–water interaction is stronger than the I–water interaction. This observation indicates that the negative end of the permanent dipole of water molecules prefers to point toward the Na1–I1 portion of (NaI)2−(H2O) and weakens the electron's attachment. Such a result is consistent with the spectrum of (NaI)2−(H2O) being shifted to a lower binding energy compared with that of bare (NaI)2−. A similar result can be found in the previous work on (NaI)n−(H2O) (n = 3, 4, 6) by Fatemi and Bloomfield.36 They reported that water could orient itself to decrease the electron affinity of the alkali halide. In isomer 1B, the water molecule interacts with the terminal Na atom (Na2) via its O atom and has one of its H atoms forming a hydrogen bond with I2. The water does not significantly distort the bare (NaI)2−, except that the Na2–I2 distance is increased by only 0.29 Å. The calculated VDE of 1B at the CCSD(T) level is 1.37 eV, close to the measurement of the VDE(X′) of 1.24 eV in our experiment. So the weak band X′ is most likely due to the contribution from isomer 1B. The most stable isomer of neutral (NaI)2(H2O) can be considered to be derived from 0A′, with an extra water molecule added via Na–O and I–H interactions.
For (NaI)2−(H2O)2, 2A, 2B, and 2C are almost degenerate in energy. In isomer 2A, the (NaI)2− unit remains a L framework with two water molecules inserted between Na1 and I1. It is noteworthy that the distance between Na1 and I1 abruptly increases to 4.59 Å, which is significantly longer than in bare (NaI)2−. The theoretical VDE of 2A calculated with the CCSD(T) method is 1.65 eV, in good agreement with the experimental VDE of the higher binding energy peak of 1.62 eV. In isomer 2B, (NaI)2− forms a pyramid-shaped unit with Na2 sitting at the apex site. The distances between Na2 and two adjacent O atoms are both 2.39 Å, shorter than those between Na1 and O atoms (2.53 Å), and I1 or I2 and its adjacent H atoms (2.49 Å). This result thus suggests that the Na2–O interaction is dominant in isomer 2B. The distances between Na2 and the two I atoms are both elongated to 5.12 Å, indicating that the Na2 atom would leave the (NaI)2− unit. The theoretical VDE of isomer 2B with CCSD(T) is 1.39 eV, close to the VDE of the lower binding peak. Isomer 2C is derived from 1A with the H atom of the second water interacting with an I atom and its O atom interacting with a Na atom. The calculated VDE of 2C is 1.13 eV with the CCSD(T) method, consistent with the experimental value of 1.18 eV of the first peak X′. Thus it is likely that both isomers 2B and 2C make contributions to the first peak at a lower binding energy and 2A contributes to the second peak at a higher binding energy. From Fig. S1 (ESI†), the relative energies between 2A and 2B changed slightly for the LC-ωPBE and MP2 methods. But the changes of the relative energies are under the uncertainties of the theoretical calculations. Thus both the LC-ωPBE and MP2 methods give reasonable results. From Fig. 5, we can see that all neutral isomers are derived from 1A′. Isomers 2A′ and 2B′ are degenerate, and 2C′ is higher than the global minimum by 0.08 eV in energy. Isomer 2A′ has a C2v symmetry, the second water interacts with another Na atom via its O atom and connects to the same I atom that interacts with the first water; 2B′ with a C2h symmetry has a similar structure except one water prefers to form a hydrogen bond with the other I atom. In 2C′, the two water molecules interact with the same Na atom.
For (NaI)2−(H2O)3, three low-lying isomers nearly degenerate in energy are found, as presented in Fig. 3. Isomer 3A is derived from 2A, with the third water molecule interacting with the Na1 atom via its O atom, and interacting with the I1 atom via one of its H atoms. The length between Na1 and I1 is 4.36 Å, longer than that in bare (NaI)2− by 1.53 Å. The calculated VDE of 3A is 1.50 eV at the CCSD(T) level of theory, in good agreement with the experimental VDE(X) of 1.59 eV. So we conclude that isomer 3A yields the VDE of the second peak X at a higher binding energy. Isomer 3B is derived from 2B, with the H atom of water interacting with the nearest I atom and the O atoms of water connecting with the adjacent Na atoms, and its calculated VDE is 1.04 eV with the CCSD(T) method. Isomer 3C is derived from 2C with the additional water sitting between Na1 and I1 and the Na1–I1 distance increases to 4.16 Å. The calculated VDE is 1.10 eV at the CCSD(T) level of theory. It is noteworthy that the calculated VDEs of 3B and 3C are both consistent with the experimental VDE (X′, 1.04 eV) of the lower binding energy peak. Therefore we conclude that isomers 3B and 3C make contributions to the lower binding energy peak. Similar to (NaI)2−(H2O)2, the relative energies between 3A and 3B also changed slightly for the LC-ωPBE and MP2 methods, and these changes are under the uncertainties of theoretical calculations (Fig. S1, ESI†). As for the neutrals, the most stable isomer 3A′ can be considered as 2A′ attaching a third water to interact with one Na atom via its O atom and to form a hydrogen bond with an I atom via one of its H atoms. Isomer 3B′ has a Cs symmetry, and is derived from isomer 2A′ with the additional water molecule interacting with one Na atom via its O atom and with the same I atom through one of its H atoms.
For (NaI)2−(H2O)4, the global minimum isomers are shown in Fig. 4 and they differ in energy by only 0.08 eV at the LC-ωPBE level. Isomers 4A and 4B can be considered as pyramid-shaped structures based on the framework (NaI)2−. Isomer 4A has a Cs symmetry, each I atom of the (NaI)2− unit interacts with three H atoms of three water molecules and the Na atoms interact with the adjacent oxygen atoms. In isomer 4B, there are three H atoms of three water molecules pointing to I1, and two H atoms of two water molecules pointing to I2. The calculated VDEs of 4A and 4B with the CCSD(T) method are 1.16 and 1.07 eV, respectively, close to the experimental VDE of 1.00 eV. So we suggest that the band features of the experiment are contributed collectively by isomers 4A and 4B. For the neutral isomers, the (NaI)2 unit of the most stable 4A′ has a C2v symmetry with four water molecules sitting around one side of the quadrilateral unit (NaI)2. The distances of both Na1⋯I2 and Na2⋯I2 abruptly increase to 4.36 Å, whereas the Na1⋯I1 and Na2⋯I1 distances are 2.96 Å, only slightly different from those in the bare (NaI)2 unit. This indicates that the water molecules' interferences induced a significant change in the (NaI)2 unit. 4B′ is derived from 3A′, just 0.02 eV higher than 4A′, the further calculated energy difference is 0.18 eV with the CCSD(T) method, and each Na atom interacts with two water molecules.
For (NaI)2−(H2O)5, two low-lying isomers derived from 4A are found. In the most stable isomer 5A, the fifth water molecule interacts with a Na atom via its O atom and interacts with the adjacent I via one of its H atoms, and the other H atom points to the O atom of the nearest water to form a water–water H-bond. The VDE of 5A is calculated to be 1.29 eV with the LC-ωPBE method. The experimental photoelectron peak is very broad and extends in the range of 0.76–1.47 eV. Thus, isomer 5A may contribute to the high EBE part of the photoelectron peak. Isomer 5B is higher in energy than 5A by only 0.05 eV, with the additional water molecule interacting with Na2 via its O atom. The calculated VDE of 5B is 1.08 eV with the LC-ωPBE method, in agreement with the experimental VDE of 1.07 eV. Considering the calculation error limit, we conclude that both 5A and 5B exist in the experiment. As for the neutral isomer, the most stable isomer 5A′ is built by attaching an additional water molecule to 4A′ by interacting with Na1 via its O atom and forming a hydrogen bond with I2. For (NaI)2−(H2O)6, two typical low-lying isomers with water–water H-bonds are found. The most stable structure 6A is derived from 5A, and the sixth water molecule interacts with I2 via one H atom and interacts with the O atom of the adjacent water to form water–water H-bonding via another H atom. The theoretical VDE of 6A (1.25 eV) calculated at the LC-ωPBE level of theory is close to the experimental VDE of 1.08 eV. As for isomer 6B, it can considered to be derived from 5B with an additional water molecule interacting with I1 and Na1 via one H atom and O atom respectively. The other H atom of the additional water interacts with the adjacent water to form a water–water H-bond. The calculated VDE of 6B (1.08 eV) is in excellent agreement with the experimental VDE. Therefore, both isomers 6A and 6B make contributions to the spectrum of the experiment. As for the neutrals of (NaI)2(H2O)6, two isomers degenerate in energy (6A′ and 6B′) are found. Isomer 6A′ is a Cs symmetry structure derived from 5A′, with a sixth water molecule sitting between Na2 and I2. The distances between I2 and the two Na atoms are both 4.41 Å, and the Na1–I1 and Na2–I1 distances are both 3.17 Å. In isomer 6B′, four water molecules sit around one side of the quadrilateral (NaI)2 unit and the other two water molecules sit between Na1 and I4. The I2–Na2, I2–Na1, I1–Na1, and I1–Na2 distances are 4.28, 4.40, 3.77, and 2.98 Å respectively. From this, we can see that the Na–I distances are significantly affected by the water molecules.
In order to understand the structural variation mechanism of the (NaI)2−(H2O)n (n = 0–6) anions versus their corresponding neutrals, we carried out a natural population analysis (NPA)54 and calculated NPA charges. The NPA charge distributions (see ESI†) show that Na2 in neutral (NaI)2(H2O)n is positively charged, 0.72 to 0.87 e, whereas the charge of Na2 in the corresponding anion (NaI)2−(H2O)n is −0.04 to −0.07 e, that is, the charge of Na2 is reduced by 0.72 to 0.91 e while the charges on the other Na and I atoms are almost unchanged, therefore the excess electron of the anions (NaI)2−(H2O)n is mainly localized on Na2. The addition of the excess electron weakens the Coulomb attraction between Na2 and the adjacent I ions compared with that in the corresponding neutral, so the (NaI)2− unit can form a L-shaped or pyramid-shaped structure rather than a ring structure like that of the neutrals. The Na2 atom can be more easily separated from the (NaI)2− unit in the pyramid-shaped structures of the anion clusters because of the weak interaction between Na2 and the two I atoms.
In addition, from the analysis of the structures, we can see that both in the anionic and the neutral isomers, water molecules prefer to stay near the Na rather than I, and I always stays out at the surface; this is similar to MI(H2O)n−(M = Li, Cs).42 Some previous work8,17,28 reported that the polarizable iodide anion is poorly solvated and presents itself at the surface of a water cluster. Our results are consistent with the previous work.
To investigate and visualize the cation–anion, cation–water, anion–water, and water–water interactions in the (NaI)2−(H2O)n clusters, we carried out a reduced density gradient (RDG) analysis. Reduced density gradient, coming from the density and its first derivative, is a very useful method to explore noncovalent interactions. Fig. 8 displays the gradient isosurfaces of the (NaI)2−(H2O)n (n = 1–6) cluster anions. From Fig. 8, we can see that the green areas localize near the terminal Na atom (Na2) in the (NaI)2−(H2O)n clusters. This indicates that the excess electron of a (NaI)2−(H2O)n cluster is mainly localized on its terminal Na atom, consistent with the result of the NPA analysis mentioned in the previous section.
As can be seen in Fig. 8, for (NaI)2−(H2O), the region between Na and I atoms, as well as that between one H atom of water and the terminal I atom, are dominated by a light green color, indicating that there are mainly weak attractive interactions in these regions; while the region between the O atom of water and its adjacent Na atom shows a blue color, indicating a strong electrostatic attraction. This is consistent with the results in the previous sections, that is, the bond length of Na–O is shorter than that of I–H. The strong Na+–water interaction would reduce the VDE of (NaI)2−(H2O) by stabilizing the product state of photodetachment, the corresponding neutral. This is responsible for the shift of VDE to a lower binding energy for (NaI)2−(H2O) compared to that of bare (NaI)2−.
For (NaI)2−(H2O)n with n = 2–4, the RDG isosurfaces of the L-shaped structures show blue color disks between the middle Na atom and the adjacent O atoms of water, revealing that Na+–water interactions are still dominant. Additionally, the regions between the terminal I atom and the neighboring H atoms of water are light blue accompanied by green, indicating that the interactions are enhanced compared with those in (NaI)2−(H2O). For the pyramid-shaped structures at n = 2–4, the isosurfaces between Na atoms and the adjacent O atoms of water show a blue color, indicating very strong electrostatic attraction between Na and water; while the regions between I atoms and the adjacent H atoms have a light-blue color accompanied by green, showing the characteristics of weak H-bonding.
As for the most stable isomers of (NaI)2−(H2O)5 and (NaI)2−(H2O)6, we can see that the interaction regions of two I atoms and their adjacent H atoms are blue accompanied by green and the interaction regions of water–water are blue; while the interaction regions of the Na atoms and their neighboring O atoms of water show a light green color. These results indicate that the I−–water and water–water interactions are considerably enhanced and are dominant in (NaI)2−(H2O)5 and (NaI)2−(H2O)6. This may explain why the VDEs of (NaI)2−(H2O)n shift toward higher EBE at n = 5–6.
Footnote |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c5cp05550d |
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