Issue 31, 2016
From the journal:

CrystEngComm

An enhanced extended hook method to realize tetranuclear metal clusters embedded in energetic metal–organic framework channels†

Yu Xiao,ab   Shuai-Hua Wang,a   Jian-Gang Xu,ab   Cai Sun,ab   Rong Li,ab   Ya-Ping Zhao,ab   Yong Yan,ab   Fa-Kun Zheng*a  and  Guo-Cong Guoa  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China
E-mail: zfk@fjirsm.ac.cn

b University of Chinese Academy of Sciences, Beijing 100039, PR China

Abstract

Rare tetranuclear Zn clusters were successfully embedded into 3D energetic metal–organic framework channels by an enhanced extended hook method. The obtained metal–organic framework exhibits not only high enthalpy of combustion and low sensitivity but also strong green fluorescence.

Graphical abstract: An enhanced extended hook method to realize tetranuclear metal clusters embedded in energetic metal–organic framework channels

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Article information

DOI
https://doi.org/10.1039/C6CE00892E
Article type
Communication
Submitted
18 Apr 2016
Accepted
04 Jul 2016
First published
04 Jul 2016

CrystEngComm, 2016,18, 5803-5806

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An enhanced extended hook method to realize tetranuclear metal clusters embedded in energetic metal–organic framework channels

Y. Xiao, S. Wang, J. Xu, C. Sun, R. Li, Y. Zhao, Y. Yan, F. Zheng and G. Guo, CrystEngComm, 2016, 18, 5803 DOI: 10.1039/C6CE00892E

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