For the first time, porous organic polymers (POPs) based on the smallest buckybowl, corannulene (BB-POPs) have been synthesized. Three POPs were synthesised via Sonogashira co-polymerization of 1,2,5,6-tetrabromocorannulene and alkyne linkers. BB-POP-3 exhibits the highest surface area (SABET = 560 m2 gā1) and CO2 adsorption of 11.7 wt%, while they retain the redox properties of corannulene.
A. A. K. Karunathilake, C. M. Thompson, S. Perananthan, J. P. Ferraris and R. A. Smaldone, Chem. Commun., 2016, 52, 12881 DOI: 10.1039/C6CC07421A
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