A reduced copper metal–organic framework (rCu-MOF) containing CuI ions was prepared by reducing raw MOFs (Cu-BTC). A series of polymer functionalizations and coupling reactions could subsequently be achieved via CuAAC click chemistry, thus demonstrating the high activity, facile recyclability and good structural stability of rCu-MOFs for catalytic applications.
Q. Fu, K. Xie, S. Tan, J. M. Ren, Q. Zhao, P. A. Webley and G. G. Qiao, Chem. Commun., 2016, 52, 12226 DOI: 10.1039/C6CC06890A
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