A palladium-catalyzed indole dearomative bisfunctionalization via a domino arylation/alkynylation sequence has been developed, which provides a reliable approach to a series of structurally diverse tetracyclic indolines bearing vicinal tertiary and quaternary stereocenters in moderate to good yields and excellent diastereoselectivities.
R. Liu, T. Xu, Y. Wang, B. Xiang, J. Gao and Y. Jia, Chem. Commun., 2016, 52, 13664 DOI: 10.1039/C6CC06262H
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