Anhydrous H2O2 reacts with organic colloidal solutions of ceria nanoparticles to form a stable surface peroxo/hydroperoxo species with the release of oleate capping ligands into solution. A new optical spectroscopic signature was identified for cerium-peroxo/hydroperoxo species in solution and correlated with solid-state IR spectroscopy and chemical reactivity.
D. Damatov and J. M. Mayer, Chem. Commun., 2016, 52, 10281 DOI: 10.1039/C6CC03790A
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