Issue 63, 2016
From the journal:

Chemical Communications

Contrasted photochromic and luminescent properties in dinuclear Pt(ii) complexes linked through a central dithienylethene unit†

Julien Boixel,*a   Yifan Zhu,b   Hubert Le Bozec,a   Mohamed Ali Benmensour,a   Abdou Boucekkine,a   Keith Man-Chung Wong,b   Alessia Colombo,c   Dominique Roberto,c   Véronique Guerchais*a  and  Denis Jacquemin*de  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, UMR-6226 CNRS-Université de Rennes 1, Campus Beaulieu, 35042 Rennes Cedex, France
E-mail: julien.boixel@univ-rennes1.fr, veronique.guerchais@univ-rennes1.fr

b Department of Chemistry, South University of Science & Technology of China, No. 1088, Tangchang Boulevard, Nanshan District, Shenzhen, Guangdong, P. R. China

c Dipartimento di Chimica, Università degli Studi di Milano and UdR INSTM di Milano, via Golgi 19, Milano, Italy

d Laboratoire CEISAM, UMR CNRS 6230, Université de Nantes, 2 rue de la houssinière, 44322 Nantes Cedex 03, France
E-mail: Denis.Jacquemin@univ-nantes.fr

e Institut Universitaire de France, 1 rue Descartes, F-75005 Paris Cedex 05, France

Abstract

We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(II) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations.

Graphical abstract: Contrasted photochromic and luminescent properties in dinuclear Pt(ii) complexes linked through a central dithienylethene unit

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Article information

DOI
https://doi.org/10.1039/C6CC03431D
Article type
Communication
Submitted
24 Apr 2016
Accepted
13 Jul 2016
First published
13 Jul 2016

Chem. Commun., 2016,52, 9833-9836

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Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit

J. Boixel, Y. Zhu, H. Le Bozec, M. A. Benmensour, A. Boucekkine, K. M. Wong, A. Colombo, D. Roberto, V. Guerchais and D. Jacquemin, Chem. Commun., 2016, 52, 9833 DOI: 10.1039/C6CC03431D

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