Issue 10, 2015
From the journal:

Journal of Materials Chemistry A

New challenge of metal–organic frameworks for high-efficient separation of hydrogen chloride toward clean hydrogen energy†

Jia Liu,ac   Wei Xia,a   Weijun Mu,ac   Peizhou Li,bc   Yanli Zhao*bc  and  Ruqiang Zou*ac  

* Corresponding authors

a Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China
E-mail: rzou@pku.edu.cn

b Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
E-mail: zhaoyanli@ntu.edu.sg

c Singapore Peking University Research Centre for a Sustainable Low-Carbon Future, 1 Create Way, Singapore 138602, Singapore

Abstract

Eleven metal–organic framework (MOF) based materials are employed for H2/HCl separation by real breakthrough experiment and molecular dynamic simulation method for the first time. Among these MOF samples, only MIL-101(Cr) and UiO-66 are regenerable and present extremely high working capacity for HCl adsorption up to 7.67 mmol g−1 with unprecedented separation coefficient up to 1363. The dynamic adsorption and separation of H2/HCl on UiO-66 and MIL-101(Cr) afford clean hydrogen energy resource with a purity of 99.997%.

Graphical abstract: New challenge of metal–organic frameworks for high-efficient separation of hydrogen chloride toward clean hydrogen energy

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4TA06832G
Article type
Communication
Submitted
12 Dec 2014
Accepted
02 Feb 2015
First published
03 Feb 2015

J. Mater. Chem. A, 2015,3, 5275-5279

Permissions

Request permissions

New challenge of metal–organic frameworks for high-efficient separation of hydrogen chloride toward clean hydrogen energy

J. Liu, W. Xia, W. Mu, P. Li, Y. Zhao and R. Zou, J. Mater. Chem. A, 2015, 3, 5275 DOI: 10.1039/C4TA06832G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements