Open Access Article
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DOI: 10.1039/C5SC90018B
(Correction)
Chem. Sci., 2015, 6, 3268-3268
Correction: Electrostatic control of regioselectivity via ion pairing in a Au(I)-catalyzed rearrangement
Vivian M.
Lau
,
Craig F.
Gorin
and
Matthew W.
Kanan
*
Department of Chemistry, Stanford University, 337 Campus Drive, Stanford, California 94305, USA. E-mail: mkanan@stanford.edu
Received
13th March 2015
, Accepted 13th March 2015
First published on 25th March 2015
Abstract
Correction for ‘Electrostatic control of regioselectivity via ion pairing in a Au(I)-catalyzed rearrangement’ by Vivian M. Lau et al., Chem. Sci., 2014, 5, 4975–4979.
The first column of values in Table 3 are incorrect. Table 3 should appear as follows:
Table 3 Calculated dipole moments of isomeric transition states leading to products 2x and 3x
|
|
||||
|---|---|---|---|---|
| R = | ρ (2x‡) (D) | ρ (3x‡) (D) | Δ|ρ| (D) |
|
| a P toluene and PCH2Cl2 are the product ratios (3x/2x) in toluene and CH2Cl2. | ||||
| Me (1b) | 4.1 | 4.0 | −0.1 | 0.9 |
| MeO (1c) | 4.1 | 4.8 | 0.7 | 1.3 |
| F (1e) | 2.9 | 5.4 | 2.5 | 3.1 |
| Cl (1a) | 2.6 | 5.9 | 3.3 | 5.0 |
| Br (1d) | 2.5 | 7.5 | 5.0 | 2.7 |
| CF3 (1f) | 2.4 | 9.0 | 6.6 | 6.3 |
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
| This journal is © The Royal Society of Chemistry 2015 |