Carbon nanotube based polymer nanocomposites: biomimic preparation and organic dye adsorption applications

Abstract

The development of highly efficient adsorbents for the removal of organic dyes from wastewater has attracted much attention recently. Surface modification of adsorbents with polymers is a general strategy for enhancement of their adsorption capability. In this work, a novel strategy of a combination of mussel inspired chemistry and SET-LRP has been developed for the fabrication of highly efficient adsorbents, poly(sodium-p-styrene sulfonate) modified multi-walled carbon nanotubes (CNTs), for the first time. The adsorption applications of these CNT based polymer nanocomposites for the removal of a cationic dye (methylene blue, MB) from a water solution were also examined. The successful preparation of these CNT based polymer nanocomposites was confirmed by a series of characterization techniques. Furthermore, the influence of adsorption parameters including contact time, concentration of MB, adsorption temperature and time has been investigated. According to the experimental data, the adsorption capacity of MB was directly proportional to the contact time, while inversely proportional to the temperature. The maximum adsorption capacity of MB for CNT-PDA-PSPSH was 160 mg g⁻¹, demonstrating the excellent adsorptive property of functional CNTs for MB. The method described in this work for the preparation of CNT based polymer nanocomposites is simple, effective and general, and could be a universal strategy for preparation of highly efficient adsorbents for environmental applications.