Facile synthesis of flower-like CoMn2O4 microspheres for electrochemical supercapacitors

Abstract

Facile synthesis of porous and hollow spinel materials is highly desirable for their extensive applications in energy storage fields. In this work, uniform and decentralized flower-like CoMn₂O₄ microspheres were synthesized and characterized for supercapacitor electrodes in neutral aqueous electrolyte. In this contribution, uniform microsphere precursors were firstly fabricated by a solvothermal method, followed by a low temperature calcination process for crystallization. A detailed study shows that the deionized (DI) water content plays an important role in the solvothermal process to optimize the morphology of the microspheres. In 1 M Na₂SO₄, the spinel electrode material has a working potential window as high as 1.1 V and a specific capacitance of 188 F g⁻¹. Besides, the electrode material exhibits excellent cycling stability by retaining 93% of its original capacitance after 1000 cycles. Therefore, the flower-like microspheres of CoMn₂O₄ spinel are promising candidates for supercapacitor applications.