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The direct sulfenylation and sulfonylation of (sp2)C–H bonds of benzamide derivatives were achieved using a Ni catalyst with the aid of an 8-aminoquinoline moiety as a bidentate directing group. These protocols represent a convenient route for the formation of valuable diaryl sulfides and sulfones in moderate to excellent yields.

Graphical abstract: Nickel-catalyzed synthesis of diarylsulfides and sulfones via C–H bond functionalization of arylamides

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