Issue 22, 2015

Writing nanopatterns with electrochemical oxidation on redox responsive organometallic multilayers by AFM

Abstract

Nanoelectrochemical patterning of redox responsive organometallic poly(ferrocenylsilane) (PFS) multilayers is demonstrated by electrochemical dip pen lithography (EDPN). Local electrochemical oxidation and Joule heating of PFS multilayers from the tip are considered as relevant mechanisms related to structure generation. The influence of applied bias potential, tip velocity, and multilayer thickness on the pattern height and width were investigated.

Graphical abstract: Writing nanopatterns with electrochemical oxidation on redox responsive organometallic multilayers by AFM

Supplementary files

Article information

Article type
Communication
Submitted
21 Feb 2015
Accepted
17 Apr 2015
First published
22 Apr 2015

Nanoscale, 2015,7, 9970-9974

Author version available

Writing nanopatterns with electrochemical oxidation on redox responsive organometallic multilayers by AFM

J. Song, M. A. Hempenius, H. Jing Chung and G. Julius Vancso, Nanoscale, 2015, 7, 9970 DOI: 10.1039/C5NR01206F

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