Issue 10, 2015

Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

Abstract

Borane-stabilized lanthanide imides have been synthesized by the reaction of lanthanide trialkyls with a bulky amine borane. X-ray crystal structures indicate the presence of 3-center-2-electron B–H–Ln bonding and Ln–arene interactions in the solid state.

Graphical abstract: Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

Supplementary files

Article information

Article type
Letter
Submitted
29 Apr 2015
Accepted
12 Jun 2015
First published
12 Jun 2015

New J. Chem., 2015,39, 7567-7570

Author version available

Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

J. Li, D. Gao, H. Hu and C. Cui, New J. Chem., 2015, 39, 7567 DOI: 10.1039/C5NJ01067E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements