Fabrication of a novel nanocomposite Ag/graphene@SiO2–NaLuF4:Yb,Gd,Er for large enhancement upconversion luminescence

Abstract

Upconversion nanocrystals have a lot of advantages over other fluorescent materials. However, their applications are still limited due to their comparatively low upconversion luminescence (UCL). In the present study, a novel nanocomposite of Ag/graphene@SiO₂–NaLuF₄:Yb,Gd,Er for enhancing UCL was fabricated successfully, and its morphology, crystalline phase, composition, and fluorescent property were investigated. It is interesting to find that the Ag/graphene@SiO₂–NaLuF₄:Yb,Gd,Er and Ag@SiO₂–NaLuF₄:Yb,Gd,Er nanocomposites showed high UCL enhancements of 52- and 10-fold compared to the control of Ag-free nanocomposite SiO₂–NaLuF₄:Yb,Gd,Er, respectively. The enhancement of 52-fold is greater than those reported in our previous studies and some papers. Moreover, the measured life times of the Ag-presented nanocrystals were longer than that of Ag-absent counterparts. These enhancements of UCL can be ascribed to the effect of metal-enhanced fluorescence, which is caused by the enhancement of the local electric field. The UCL intensity of Ag/graphene@SiO₂-NaLuF₄:Yb,Gd,Er was 5.2-fold higher than that of Ag@SiO₂–NaLuF₄:Yb,Gd,Er, indicating that graphene presented in the fabricated nanocomposite structure favors metal-enhanced UCL. The small-sized Ag nanoparticles anchored on the graphene sheet mutually enhanced each other's polarizability and surface plasmon resonance, resulting in a big metal-enhanced UCL. This study provides a new strategy for effectively enhancing the UCL of upconversion nanocrystals. The enhancement potentially increases the overall upconversion nanocrystal detectability for highly sensitive biological, medical, and optical detections.