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Metallopeptoid catalysts incorporating phenanthroline–copper and TEMPO, and at least one non-catalytic group perform in the oxidation of various benzylic, allylic and aliphatic primary alcohols with a TON of up to 16 times higher than a mixture of the two catalytic groups or the peptoid dimer that is lacking the non-catalytic group.

Graphical abstract: Metallopeptoids as efficient biomimetic catalysts

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