Issue 59, 2015

Visible light promoted hydration of alkynes catalyzed by rhodium(iii) porphyrins

Abstract

Visible light promoted hydration of a wide scope of alkynes to ketones catalyzed by rhodium(III) porphyrin complexes was described. The key intermediate β-carbonyl alkyl was observed and independently synthesized. The rate of photolysis is over two orders of magnitude faster than that of the thermal process.

Graphical abstract: Visible light promoted hydration of alkynes catalyzed by rhodium(iii) porphyrins

Supplementary files

Article information

Article type
Communication
Submitted
14 May 2015
Accepted
14 Jun 2015
First published
16 Jun 2015

Chem. Commun., 2015,51, 11896-11898

Author version available

Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins

X. Liu, L. Liu, Z. Wang and X. Fu, Chem. Commun., 2015, 51, 11896 DOI: 10.1039/C5CC04015A

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