Issue 56, 2015

Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption

Abstract

A combined experimental and computational study has revealed the interplay between the framework pore size and functionality on the CO2 adsorption performance of zirconium-based MIL-140 frameworks. The CO2–sorbent interactions were markedly influenced by pore-confinement effects which arise from the π-stacked arrangement of the ligands within the framework backbone.

Graphical abstract: Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2015
Accepted
07 Jun 2015
First published
08 Jun 2015

Chem. Commun., 2015,51, 11286-11289

Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption

W. Liang, R. Babarao, T. L. Church and D. M. D'Alessandro, Chem. Commun., 2015, 51, 11286 DOI: 10.1039/C5CC02539G

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