Hanping Zhang, Tao Yang, Xin Wu, Yisen Zhou, Chao Yang, Tian Zhu and Rulin Dong
Chem. Commun., 2015,51, 7294-7297
DOI:
10.1039/C5CC00575B,
Communication
We propose an aqueous rechargeable Zn–Cu Daniell-type battery. In this system, Li+ prefers to conduct currents rather than react with the electrodes, while the Zn–Cu electrode couples engage in their electrochemical reactions free from conducting currents. Here Li+ performs like a messenger and thus could be called the electrochemical messenger.