G. C.
Schmidt
*a,
D.
Höft
a,
K.
Haase
a,
A. C.
Hübler
a,
E.
Karpov
b,
R.
Tkachov
b,
M.
Stamm
bc,
A.
Kiriy
*b,
F.
Haidu
d,
D. R. T.
Zahn
d,
H.
Yan
e and
A.
Facchetti
fg
aInstitute for Print and Media Technology, Chemnitz University of Technology, 09107 Chemnitz, Germany. E-mail: georg.schmidt@mb.tu-chemnitz.de
bLeibniz-Institut für Polymerforschung Dresden e.V, Hohe Straße 6, 01069 Dresden, Germany. E-mail: kiriy@ipfdd.de
cTechnische Universität Dresden, Center for Advancing Electronics Dresden (cfaed), 01062, Dresden, Germany
dSemiconductor Physics, Chemnitz University of Technology, 09107 Chemnitz, Germany
eDepartment of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay, KowLoon, Hong Kong
fPolyera Corporation, 8045 Lamon Avenue, Skokie, Illinois 60077, USA
gKing Abdulaziz University, Jeddah 21589, Saudi Arabia
First published on 16th May 2014
The semiconducting properties of a bithiophene-naphthalene diimide copolymer (PNDIT2) prepared by Ni-catalyzed chain-growth polycondensation (P1) and commercially available N2200 synthesized by Pd-catalyzed step-growth polycondensation were compared. Both polymers show similar electron mobility of ∼0.2 cm2 V−1 s−1, as measured in top-gate OFETs with Au source/drain electrodes. It is noteworthy that the new synthesis has several technological advantages compared to traditional Stille polycondensation, as it proceeds rapidly at room temperature and does not involve toxic tin-based monomers. Furthermore, a step forward to fully printed polymeric devices was achieved. To this end, transistors with PEDOT:PSS source/drain electrodes were fabricated on plastic foils by means of mass printing technologies in a roll-to-roll printing press. Surface treatment of the printed electrodes with PEIE, which reduces the work function of PEDOT:PSS, was essential to lower the threshold voltage and achieve high electron mobility. Fully polymeric P1 and N2200-based OFETs achieved average linear and saturation FET mobilities of >0.08 cm2 V−1 s−1. Hence, the performance of n-type, plastic OFET devices prepared in ambient laboratory conditions approaches those achieved by more sophisticated and expensive technologies, utilizing gold electrodes and time/energy consuming thermal annealing and lithographic steps.
n-Type (or electron-conducting) polymers are essential components in organic devices, such as ambipolar and n-channel field-effect transistors or organic photovoltaics.6 Rylene diimide alternating main chain copolymers, such as those based on naphthalene diimides, are currently evolving as an intriguing class of electron-conducting materials.7 For example, a bithiophene-naphthalene diimide copolymer (PNDIT2, also known as P(NDI2OD-T2) and commercially available as Activink N2200) was reported to yield high electron mobilities under ambient conditions.8 Furthermore, PNDIT2, and its analogous, were shown to be promising electron acceptors for all-polymer solar cells.9 Semiconducting conjugated polymers, including PNDIT2, are generally synthesized by step-growth polymerizations, most often by Pd-catalyzed Stille polycondensation.7 Conjugated polymers synthesized in such a way frequently suffer from a low degree of control over molecular weight (Mw). This often results in batch-to-batch variations and altered semiconducting properties, which is undesirable for optoelectronic applications. Another important drawback of step-growth polycondensations is that they are relatively slow processes so that synthesis of high enough Mw polymers usually requires long reaction times and high reaction temperatures.10 The formation of toxic tin-based by-products is another important concern of the Stille polycondensation.11
Recently, we introduced a novel nickel-catalyzed chain-growth polymerization of an anion-radical monomer that allows preparation of PNDIT2 with controlled Mw and relatively low polydispersity index, PDI (Scheme 1).12 Additional advantage of the developed polymerization is that it proceeds relatively fast (within a couple of hours) and does not use toxic tin-based monomers. To this regard, the newly-developed synthetic methodology is a promising technology for potential commercial applications. However, the semiconducting properties of PNDIT2 prepared by means of the new method were not tested in OFETs. The present work compares the semiconducting performance of PNDIT2 obtained by chain-growth tin-free polymerization and commercially available PNDIT2 prepared by Pd-catalyzed step-growth Stille polycondensation (here indicated as N2200). Furthermore, we were particularly interested in evaluating their semiconducting properties in fully-organic, printed OFET devices. Our data demonstrate the first report enabling high-mobility n-type FETs using printed PEDOT:PSS electrodes.
PEDOT:PSS is a well-known conductor exhibiting good hole injection properties. Thus, when using PEDOT:PSS as an electron injecting material there is a need for surface modification to fine-tune the work function. Therefore, the PEDOT:PSS electrodes were optionally treated by ethoxylated poly(ethyleneimine) (PEIE) to reduce the work function of the electrodes.15 This process step is quite important for good electron injection, because of the high work function of printed PEDOT:PSS source/drain electrodes which was measured to be 5.4–5.7 eV.14 PEIE, 80% ethoxylated, dissolved in water at a concentration of 35–40 wt% was received from Sigma and further diluted with butyl glycol to a final concentration of 0.4 wt%. This solution was spincoated on top of the PEDOT:PSS source/drain electrodes, next the film was dried at 110 °C for 5 min. Afterwards, either P1 or N2200 were deposited from a 1 wt% solution in xylene by means of spincoating, followed by a drying step at 110 °C for 10 min. As dielectric CYTOP CTL-809M was used as received and applied via spincoating, resulting in a layer thickness of ∼2 μm after drying at 110 °C for 10 min. This leads to a maximum specific gate capacitance in accumulation regime of 1.1–1.2 nF cm−2. The higher thickness of the dielectric was chosen to prevent high gate leakage current for the printed devices. Finally, the gate electrodes were flexo-printed at a laboratory printing press (Flexiproof 100, RK Print) with a copper micro-particle ink received from Eckart. To achieve sufficient wetting of the ink printed onto the hydrophobic CYTOP layer, the surface tension of the formulation was reduced by adding perfluoro surfactants. Additionally, the printing settings velocity and pressure between the rollers were optimized to get homogenous and well structured gate electrodes. Due to the relatively low pressure between the printing rollers and the flexible substrate, flexography prevents the sensitive organic layers from very high mechanical stress while printing the gate. The channel length and the channel width of these OFETs were 20 μm and 30000 μm, respectively. All process steps and measurements were executed under ambient laboratory conditions in air.
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Fig. 3 UPS spectra of printed PEDOT:PSS layers with and without PEIE layer on top. From the secondary electron cutoff a work function of −4.5 eV and −5.4 eV can be calculated. |
However, it is likely the work function of PEDOT:PSS is too high for efficient injection of electrons into the LUMO of organic n-type semiconductors. It was recently demonstrated that the work function of conductors, including metals, transparent conductive metal oxides and conducting polymers can be significantly reduced by adsorption of surface modifiers containing aliphatic amine groups, such as ethoxylated poly(ethyleneimine) (PEIE).15 Thus, to rationalize the performance of our devices (vide infra), UPS measurements of printed PEDOT:PSS layers with and without PEIE coating were carried out and the results are shown in Fig. 3. These data indicate a considerable decrease of the PEDOT:PSS work function upon PEIE treatment from (−5.4 ± 0.1) eV to (−4.5 ± 0.1) eV.
Therefore, in this work, the OFET performances of n-channel polymers such as P1 and N2200 were evaluated for the first time using printed PEDOT:PSS electrodes with and without PEIE treatment. These devices have been fabricated by spin-coating the semiconductor (P1 or N2200) and the dielectric (CYTOP) on top of the source/drain electrodes. Finally, the gate electrodes (copper-particle ink) were printed by flexography. Typical output and transfer curves of these OFETs are given in Fig. 4. It becomes obvious that the PEIE treatment strongly improves the electrical contact between the polymeric electrodes and the semiconductor. The devices without PEIE injection layer (Fig. 4a and c) required a very high source/drain voltage Vds to overcome the high contact resistance resulting from the mismatch between PEDOT:PSS (−5.4 eV) and the LUMO level of PNDIT2 (−4.0 eV). Thus, the threshold voltage of the devices without PEIE treatment was found to be +20.0 and +22.8 V for N2200 and P1, respectively.
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Fig. 4 Output (left) and transfer (right) curves of OFETs made with (a) N2200 without PEIE, (b) N2200 with PEIE treatment, (c) P1 without PEIE, and (d) P1 with PEIE treatment. |
In contrast, OFETs fabricated with PEIE show a typical linear increase of the drain current Id for low Vds as the result of the decreased PEDOT:PSS work function and the threshold voltage of these devices decreases to +9.9 and +10.6 V, respectively. Besides other important parameters, a low threshold voltage is essential to decrease the supply voltage for printed circuits based on fully polymeric/organic FETs. Thus, our results strongly indicate the possibility to print fully polymeric n-type OFETs.
Fully polymeric N2200-based OFETs with the PEIE treatment achieved mean linear and saturation electron mobilities of 0.08 and 0.05 cm2 V−1 s−1, respectively (Table 1). Very similar results could be obtained when using P1 instead of N2200, in which both mobilities in the linear and saturation regimes were found to be 0.08 cm2 V−1 s−1 as well. Take notice that these improved mobility values are not significantly influenced by different gate leakage current levels (Ig,max < 10 nA). These mobility values are somewhat lower than those achieved for OFETs based on gold electrodes. However, our all-polymeric devices, which include a flexible substrate, were prepared under ambient laboratory conditions in air and without thermal evaporation and lithographic processing steps. Interestingly, the significant ambipolar transport observed for P1-based OFETs and gold electrodes was found for devices without PEIE treatment. The ambipolar transport was suppressed by the PEIE treatment of the electrodes indicating the strong hole blocking property of PEIE.
Semiconductor | PEIE | μ e,lin (cm2 V−1 s−1) | μ e,sat (cm2 V−1 s−1) | V th (V) | I ON/IOFF |
---|---|---|---|---|---|
N2200 (6 OFETs) | No | 0.035 ± 0.009 | 0.077 ± 0.023 | 20.0 ± 0.9 | 2003 ± 342 |
N2200 (7 OFETs) | Yes | 0.080 ± 0.028 | 0.052 ± 0.023 | 9.9 ± 0.8 | 61 ± 12 |
P1 (7 OFETs) | No | 0.037 ± 0.008 | 0.075 ± 0.019 | 22.8 ± 1.2 | 1250 ± 1110 |
P1 (7 OFETs) | Yes | 0.086 ± 0.014 | 0.080 ± 0.030 | 10.6 ± 1.4 | 30 ± 15 |
An overview of all electrical parameters for the OFETs fabricated with PEDOT:PSS source/drain electrodes are given in Table 1. Clearly our results indicate that PEIE treatment greatly improves electron injection, reduces the threshold voltage and enhances the carrier mobility. However, Table 1 clearly indicates that the current on–off ratios decrease upon PEIE treatment, a result originating by the increased off-current. Since the PEIE coating is not only present on top of the electrodes but also in the channel area below the semiconductor, PEIE doping of the semiconductor leads to a higher intrinsic conductivity and thus reduced current on–off ratio. The doping effect was mentioned earlier by Zhou and co-workers.15 However, this drawback could be overcome by selective treatment of the electrical contacts by printing PEIE instead of spin-coating the formulation. Furthermore, fine patterning of the semiconductor, as required for circuit application, will further enhance the on–off ratio.
Finally, it is noteworthy to point out that the new synthesis has several technological advantages compared to traditional Stille polycondensation, as it proceeds fast at room temperature and does not involve toxic tin-based monomers. As such, this is a substantial step toward commercialization of fully plastic transistors.
This journal is © The Royal Society of Chemistry 2014 |