With the use of chiral tridentate P,N,N ligand, copper-catalyzed enantioselective propargylic substitution of propargylic acetates with enamines has been achieved, giving the corresponding propargylic ketones in high yields and with excellent enantioselectivities.
B. Wang, C. Liu and H. Guo, RSC Adv., 2014, 4, 53216 DOI: 10.1039/C4RA09431J
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