Issue 86, 2014

The formation of HOCO in the coadsorption of water and carbon monoxide on Pt3Ni(111)

Abstract

High-resolution electron energy loss spectroscopy has been used to study the coadsorption of water and carbon monoxide at the Pt3Ni(111) surface. The analysis of the vibrational spectrum indicates the reaction between coadsorbates (CO and OH groups of ice) with the formation of HOCO. Di-σ-trans-HOCO species are stabilized on the surface at up to 165 K. For higher temperature, HOCO desorbs from the surface.

Graphical abstract: The formation of HOCO in the coadsorption of water and carbon monoxide on Pt3Ni(111)

Article information

Article type
Communication
Submitted
04 Aug 2014
Accepted
15 Sep 2014
First published
15 Sep 2014

RSC Adv., 2014,4, 45641-45646

The formation of HOCO in the coadsorption of water and carbon monoxide on Pt3Ni(111)

A. Politano and G. Chiarello, RSC Adv., 2014, 4, 45641 DOI: 10.1039/C4RA08066A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements