Issue 23, 2014
From the journal:

Organic & Biomolecular Chemistry

Metal-free aerobic oxidative C–N bond cleavage of tertiary amines for the synthesis of N-heterocycles with high atom efficiency†

Xiuling Chen,a   Tieqiao Chen,a   Yongbo Zhou,*a   Daoqing Han,a   Li-Biao Hana  and  Shuang-Feng Yin*a  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, P. R. China
E-mail: zhouyb@hnu.edu.cn, sf_yin@hnu.edu.cn
Fax: (+) 86-731-88821171

Abstract

An efficient metal-free aerobic oxidative C–N bond cleavage of tertiary amines has been developed to construct N-heterocycles using molecular oxygen as the sole oxidant with high atom efficiency, in which all of the three alkyl groups in tertiary amines can be utilized and transformed into N-heterocycles.

Graphical abstract: Metal-free aerobic oxidative C–N bond cleavage of tertiary amines for the synthesis of N-heterocycles with high atom efficiency

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Article information

DOI
https://doi.org/10.1039/C4OB00578C
Article type
Communication
Submitted
17 Mar 2014
Accepted
14 Apr 2014
First published
14 Apr 2014

Org. Biomol. Chem., 2014,12, 3802-3807

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Metal-free aerobic oxidative C–N bond cleavage of tertiary amines for the synthesis of N-heterocycles with high atom efficiency

X. Chen, T. Chen, Y. Zhou, D. Han, L. Han and S. Yin, Org. Biomol. Chem., 2014, 12, 3802 DOI: 10.1039/C4OB00578C

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