Issue 5, 2014
From the journal:

New Journal of Chemistry

Humidity dependency of the thermal phase transition of a cyano bridged Co–W bimetal assembly†

Noriaki Ozaki,a   Hiroko Tokoro,ab   Yasuto Miyamotoa  and  Shin-ichi Ohkoshi*ac  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

b NEXT, Japan Society for the Promotion of Science (JSPS), 8 Ichibancho, Chiyoda-ku, Tokyo 102-8472, Japan

c CREST, Japan Science and Technology Agency (JST), K's Gobancho, 7 Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan

Abstract

The phase transition of a cyano-bridged Co–W bimetal assembly Co3[W(CN)8]2(4-methylpyridine)2(pyrimidine)2·xH2O depends on the humidity. This humidity responsivity is attributed to changes in the internal pressure due to the absorption (or desorption) of water molecules in the interstitial sites of the cyano-bridged three-dimensional network.

Graphical abstract: Humidity dependency of the thermal phase transition of a cyano bridged Co–W bimetal assembly

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Article information

DOI
https://doi.org/10.1039/C3NJ01656K
Article type
Letter
Submitted
30 Dec 2013
Accepted
10 Feb 2014
First published
13 Feb 2014

New J. Chem., 2014,38, 1950-1954

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Humidity dependency of the thermal phase transition of a cyano bridged Co–W bimetal assembly

N. Ozaki, H. Tokoro, Y. Miyamoto and S. Ohkoshi, New J. Chem., 2014, 38, 1950 DOI: 10.1039/C3NJ01656K

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