Issue 25, 2014
From the journal:

Dalton Transactions

[CNN]-pincer nickel(ii) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C–Cl bonds†

Yunqiang Sun,a   Xiaoyan Lia  and  Hongjian Sun*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Shanda Nanlu 27, 250199 Jinan, People's Republic of China
E-mail: hjsun@sdu.edu.cn

Abstract

Three novel [CNN]-pincer nickel(II) complexes with NHC-amine arms were synthesized in three steps. Complex 5b was proven to be an efficient catalyst for the Kumada coupling of aryl chlorides or aryl dichlorides under mild conditions.

Graphical abstract: [CNN]-pincer nickel(ii) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C–Cl bonds

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Article information

DOI
https://doi.org/10.1039/C4DT00461B
Article type
Communication
Submitted
13 Feb 2014
Accepted
17 Apr 2014
First published
24 Apr 2014

Dalton Trans., 2014,43, 9410-9413

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[CNN]-pincer nickel(II) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C–Cl bonds

Y. Sun, X. Li and H. Sun, Dalton Trans., 2014, 43, 9410 DOI: 10.1039/C4DT00461B

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