Thermotropic cubic and tetragonal phases made of rod-like molecules

Abstract

Systematic studies on three dimensionally ordered liquid crystalline phases of different cubic and tetragonal symmetries are presented. The structures of the phases are determined by reconstruction of the electron density distribution from the X-ray diffraction patterns. The known models for electron densities in cubic structures were used whereas a new theoretical model for the structure of the tetragonal phase, which shows good agreement with the experimentally obtained electron densities, was proposed. For the first time a continuous phase transition between three dimensional phases with tetragonal and monoclinic symmetries was observed for an optically pure compound.