A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs†
Abstract
Three porous coordination polymers with a simplified formula of [M4(μ4-Cl)L2]·nGuest (M = Cu, Cd) based on two adamantane-derived tetrahedral tetrazolate ligands were synthesized. Along with one known representative, the row of compounds establishes a new isoreticular series with fluorite as the underlying net.