José Martínez-Lillo, John Kong, Wdeson P. Barros, Juan Faus, Miguel Julve and Euan K. Brechin
Chem. Commun., 2014,50, 5840-5842
DOI:
10.1039/C4CC01564A,
Communication
A new chloro-bridged heterobimetallic Cu(II)Re(IV) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (1·MeCN) has been prepared and magnetostructurally characterised. Compound 1 is the first example of the [ReIVCl6]2− anion acting as a metalloligand towards a paramagnetic metal ion.