Tripodal cationic N-donor ligands exhibit sterically controlled self-assembly of tetrahedral M6L4 coordination cages that promote selective anion encapsulation (PF6− > OTf−) in the solid state. The described method is a potential template for stepwise assembly of hetero-ligand coordination cages and polymers.
A. Peuronen, S. Forsblom and M. Lahtinen, Chem. Commun., 2014, 50, 5469 DOI: 10.1039/C3CC49663E
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