Issue 40, 2014

Oxidative C(sp3)–H bond cleavage, C–C and C[double bond, length as m-dash]C coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

Abstract

Dimethyl- and diphenylplatinum(II) fragments PtIIR2 (R = Me, Ph) enable facile and efficient oxidative C(sp3)–H bond cleavage and stepwise C–C and C[double bond, length as m-dash]C coupling at the boron atom of a coordinated 1,5-cyclooctanediyldi(2-pyridyl)borato ligand with O2 as the sole oxidant.

Graphical abstract: Oxidative C(sp3)–H bond cleavage, C–C and C [[double bond, length as m-dash]] C coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

Supplementary files

Article information

Article type
Communication
Submitted
29 Sep 2013
Accepted
08 Nov 2013
First published
11 Nov 2013

Chem. Commun., 2014,50, 5376-5378

Author version available

Oxidative C(sp3)–H bond cleavage, C–C and C[double bond, length as m-dash]C coupling at a boron center with O2 as the oxidant mediated by platinum(II)

S. Pal, P. Y. Zavalij and A. N. Vedernikov, Chem. Commun., 2014, 50, 5376 DOI: 10.1039/C3CC47445C

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