Issue 22, 2013
From the journal:

Journal of Materials Chemistry A

Organic electron-rich N-heterocyclic compound as a chemical bridge: building a Brönsted acidic ionic liquid confined in MIL-101 nanocages†

Qun-xing Luo,a   Min Ji,*a   Mei-heng Lu,a   Ce Hao,a   Jie-shan Qiua  and  Yan-qin Lia  

* Corresponding authors

a School of Chemistry, Dalian University of Technology, Dalian, People's Republic of China
E-mail: jimin@dlut.edu.cn
Fax: +86-411-84986329
Tel: +86-411-84986329

Abstract

A novel functionalized MOF material, Brönsted acidic ionic liquid (BAIL) confined inside well-defined MIL-101 nanocages, was developed for the first time based on the tandem post-synthetic strategy. The catalytic performance of BAIL confined in MIL-101 material was evaluated by using the acetalization of benzaldehyde with glycol as a probe reaction. The resulting BAIL/MIL-101 material exhibited superior catalytic performance, which is mainly due to the combination of the advantageous merits of ionic liquid catalyst with the desirable microenvironment in the MIL-101 nanocages.

Graphical abstract: Organic electron-rich N-heterocyclic compound as a chemical bridge: building a Brönsted acidic ionic liquid confined in MIL-101 nanocages

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Article information

DOI
https://doi.org/10.1039/C3TA10975E
Article type
Communication
Submitted
08 Mar 2013
Accepted
12 Apr 2013
First published
12 Apr 2013

J. Mater. Chem. A, 2013,1, 6530-6534

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Organic electron-rich N-heterocyclic compound as a chemical bridge: building a Brönsted acidic ionic liquid confined in MIL-101 nanocages

Q. Luo, M. Ji, M. Lu, C. Hao, J. Qiu and Y. Li, J. Mater. Chem. A, 2013, 1, 6530 DOI: 10.1039/C3TA10975E

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