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Morphology and size of poly(m-phenylenediamine) (PmPD) can be tuned readily with conventional chemical oxidation by introducing methanol (MeOH). Increasing MeOH content facilitates the formation of one-dimensional (1D) PmPD microstructures. Typically, when the MeOH content is up to 100%, 1D nanorods were formed, displaying the Ag+ absorbability of 2073 mg g−1.

Graphical abstract: Methanol-induced formation of 1D poly(m-phenylenediamine) by conventional chemical oxidative polymerization exhibiting superior Ag+ adsorption ability

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