Issue 22, 2013
From the journal:

RSC Advances

Probing the role of weaker interactions in immobilization of solvents in a new class of supramolecular gelator†

Priyanka Yadav,a   Dalbir Kour,b   Vivek K. Gupta,b   Rajnikant *b  and  Amar Ballabh*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara, Gujarat, India
E-mail: bamar.chem@gmail.com
Fax: 912652795569
Tel: 912652795552

b X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi-180 006, India
E-mail: rkvk.paper11@gmail.com
Fax: +91 191 243 2051
Tel: +91 191 243 2051

Abstract

A new class of thiazole based organogelator was synthesized and characterized by various techniques such as VT-NMR, IR, single crystal and powder X-ray diffraction. The role of unusual H-bond interactions such as C–H⋯N and van der Waals interactions were probed as driving forces for physical gelation of various polar and non-polar solvents. A structure-property correlation between various derivatives of thiazole was explored for their gelation or non-gelation behaviour.

Graphical abstract: Probing the role of weaker interactions in immobilization of solvents in a new class of supramolecular gelator

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Article information

DOI
https://doi.org/10.1039/C3RA40738A
Article type
Paper
Submitted
22 Nov 2012
Accepted
21 Mar 2013
First published
25 Mar 2013

RSC Adv., 2013,3, 8417-8421

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Probing the role of weaker interactions in immobilization of solvents in a new class of supramolecular gelator

P. Yadav, D. Kour, V. K. Gupta, R. and A. Ballabh, RSC Adv., 2013, 3, 8417 DOI: 10.1039/C3RA40738A

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