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Abstract | Cited by

We herein describe a novel method for the synthesis of thioamides by a three component condensation of alkynyl bromides, amines, and Na2S·9H2O. The developed method is applicable for a wide range of amines and alkynyl bromides bearing different functional groups furnishing the corresponding products in moderate to excellent yields.

Graphical abstract: Synthesis of thioamides via one-pot A3-coupling of alkynyl bromides, amines, and sodium sulfide

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