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An active and stable magnetically separable Pd nanocatalyst was prepared and characterized. The nanocatalyst exhibited excellent activities and reusabilities in aqueous phase processes including the O-arylation of phenols and Sonogashira cross-coupling reactions. The proposed protocol features mild reaction conditions and an extraordinary simplicity and efficiency using NaOH as base in water.

Graphical abstract: A highly stable and active magnetically separable Pd nanocatalyst in aqueous phase heterogeneously catalyzed couplings

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