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We report synthesis of a hetero-dinuclear metal complex in a four-fold rotaxane, in which a Cu2+porphyrin and a Zn2+phthalocyanine are cofacially stacked. Interaction between the two metal complexes in the rotaxane was investigated by a UV-Vis absorption spectral study.

Graphical abstract: Synthesis of a hetero-dinuclear metal complex in a porphyrin/phthalocyanine four-fold rotaxane

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