Issue 23, 2013
From the journal:

Dalton Transactions

A chiral 2p–3d heterometallic azido complex with 2,6-pyridinedicarboxylate as the co-ligand showing magnetic order†

Jiong-Peng Zhao,ab   Qian Yang,b   Song-De Han,b   Jie Han,b   Ran Zhao,b   Bo-Wen Hub  and  Xian-He Bu*b  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

b Department of Chemistry and TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China
E-mail: buxh@nankai.edu.cn
Fax: (+86) 22-23502458

Abstract

A new chiral 3D heterometallic coordination polymer [NaCo2(L)2(N3)·(MeOH)]∞ (1) (L = 2,6-pyridinedicarboxylate) was synthesized and characterized magnetically. Ferro- and antiferromagnetic interactions co-exist in 1, which results in a magnetic phase transition at the high temperature of 29 K.

Graphical abstract: A chiral 2p–3d heterometallic azido complex with 2,6-pyridinedicarboxylate as the co-ligand showing magnetic order

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Article information

DOI
https://doi.org/10.1039/C3DT50835H
Article type
Communication
Submitted
28 Mar 2013
Accepted
29 Mar 2013
First published
03 Apr 2013

Dalton Trans., 2013,42, 8201-8204

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A chiral 2p–3d heterometallic azido complex with 2,6-pyridinedicarboxylate as the co-ligand showing magnetic order

J. Zhao, Q. Yang, S. Han, J. Han, R. Zhao, B. Hu and X. Bu, Dalton Trans., 2013, 42, 8201 DOI: 10.1039/C3DT50835H

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