Issue 24, 2013
From the journal:

Dalton Transactions

Dimeric copper(ii) complex of a new Schiff baseligand: Effect of morphology on the catalytic oxidation of aromatic alcohol†

Ravinder Kumar,a   Kuldeep Mahiyaa  and  Pavan Mathur*a  

* Corresponding authors

a Department of Chemistry, University of Delhi, Delhi-110007, India
E-mail: pavanmat@yahoo.co.in
Fax: +91 1127666605
Tel: +91 1127667725 X138l

Abstract

An antiferromagnetically coupled, dimeric μ-naphthanoxo bridged copper(II) complex is used heterogeneously to catalyze oxidation of p-chlorobenzylalcohol to aldehyde selectively. PL and PXRD studies reveal that during recycling the catalyst remains essentially intact. However loss of catalytic efficiency upon reuse is in consonance with a loss in morphology as indicated by SEM.

Graphical abstract: Dimeric copper(ii) complex of a new Schiff base ligand: Effect of morphology on the catalytic oxidation of aromatic alcohol

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Article information

DOI
https://doi.org/10.1039/C3DT50348H
Article type
Communication
Submitted
04 Feb 2013
Accepted
11 Apr 2013
First published
12 Apr 2013

Dalton Trans., 2013,42, 8553-8557

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Dimeric copper(II) complex of a new Schiff base ligand: Effect of morphology on the catalytic oxidation of aromatic alcohol

R. Kumar, K. Mahiya and P. Mathur, Dalton Trans., 2013, 42, 8553 DOI: 10.1039/C3DT50348H

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