Issue 24, 2013

Dimeric copper(ii) complex of a new Schiff baseligand: Effect of morphology on the catalytic oxidation of aromatic alcohol

Abstract

An antiferromagnetically coupled, dimeric μ-naphthanoxo bridged copper(II) complex is used heterogeneously to catalyze oxidation of p-chlorobenzylalcohol to aldehyde selectively. PL and PXRD studies reveal that during recycling the catalyst remains essentially intact. However loss of catalytic efficiency upon reuse is in consonance with a loss in morphology as indicated by SEM.

Graphical abstract: Dimeric copper(ii) complex of a new Schiff base ligand: Effect of morphology on the catalytic oxidation of aromatic alcohol

Supplementary files

Article information

Article type
Communication
Submitted
04 Feb 2013
Accepted
11 Apr 2013
First published
12 Apr 2013

Dalton Trans., 2013,42, 8553-8557

Dimeric copper(II) complex of a new Schiff base ligand: Effect of morphology on the catalytic oxidation of aromatic alcohol

R. Kumar, K. Mahiya and P. Mathur, Dalton Trans., 2013, 42, 8553 DOI: 10.1039/C3DT50348H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements