Reactivity of polynuclear palladium carboxylate complexes towards acetonitrile: synthesis and X-ray study of Pd2(C6H4-o-C(
NH)CH3)2(CH3CO2)2 and Pd5(CH3C(
N)OC(
N)CH3)(NO)(NO2)x(RCO2)7−x†
Abstract
Reactions of the polynuclear palladium carboxylate complexes (binary palladium carboxylates and palladium nitrosyl carboxylates) with NH)CH3)2(CH3CO2)2 containing molecules of orthometallated 1-phenylethanimine formed as a result of C–C-coupling of
N)OC(
N)CH3)(NO)(NO2)x(RCO2)7−x clusters. Structures of all the complexes contained products of acetonitrile transformations and a new