Issue 8, 2013
From the journal:

CrystEngComm

Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach†

Sergio J. Garibay,a   Mitchell H. Weston,a   Joseph E. Mondloch,a   Yamil J. Colón,b   Omar K. Farha,*a   Joseph T. Hupp*a  and  SonBinh T. Nguyen*a  

* Corresponding authors

a Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL, USA
E-mail: o-farha@northwestern.edu, j-hupp@northwestern.edu, stn@northwestern.edu
Fax: +1 847-467-1425
Tel: +1 847-467-4934

b Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL, USA

Abstract

Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1–CH2NH2, obtained through the post-synthesis deprotection of PAF-1–CH2–phthalimide, has been shown to exceed that of PAF-1.

Graphical abstract: Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

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Article information

DOI
https://doi.org/10.1039/C2CE26595H
Article type
Communication
Submitted
01 Oct 2012
Accepted
18 Oct 2012
First published
22 Oct 2012

CrystEngComm, 2013,15, 1515-1519

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Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

S. J. Garibay, M. H. Weston, J. E. Mondloch, Y. J. Colón, O. K. Farha, J. T. Hupp and S. T. Nguyen, CrystEngComm, 2013, 15, 1515 DOI: 10.1039/C2CE26595H

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