Fuyi Zhang, Liming Wang, Cui Zhang and Yufen Zhao
Chem. Commun., 2014,50, 2046-2048
DOI:
10.1039/C3CC48806C,
Communication
1,2-Dideoxy-2-C-diphenylphosphinylglycopyranosides were first synthesized by the novel Mn(II)–air promoted reaction of diphenylphosphine oxide with various glycals in high yields with excellent regio- and stereoselectivities, which was clarified as a radical addition reaction controlled by the oxygen of vinyl ether.