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Nucleophilic substitution of 1,6,7,12-tetrachloro perylene bisimide (PBI) with n-butanethiol provided a novel, highly twisted PBI bearing four sulphur coordination sites at the bay positions, from which silver and palladium complexes were prepared.

Graphical abstract: Transition metal complexes of axially chiral tetrathioether bay-substituted perylene bisimide dyes

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