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ITO/Pb(Zr,Ti)O3 contacts and Ag nanoparticles were used to construct a novel ferroelectric film photocathode exhibiting a stable short-circuit photocurrent of 110 μA cm−2 and an open-circuit voltage of 0.76 V under 100 mW cm−2 Xe-lamp illumination and zero-bias versus SCE.

Graphical abstract: Photocathodic behavior of ferroelectric Pb(Zr,Ti)O3 films decorated with silver nanoparticles

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