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Boron-modified pyrrole-based anion receptors (catechol–boron and diphenylboron dipyrrolyldiketone derivatives) formed planar receptor–anion complexes, leading to charge-by-charge assemblies with planar cations, as in the corresponding difluoroboron derivative.

Graphical abstract: Ion-based materials of boron-modified dipyrrolyldiketones as anion receptors

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