Issue 39, 2013
From the journal:

Chemical Communications

Divergent reactivity of nitric oxide with metal–metal quintuple bonds†‡

Pei-Fang Wu,a   Shih-Cheng Liu,a   Yun-Jen Shieh,a   Ting-Shen Kuo,b   Gene-Hsiang Lee,c   Yu Wangc  and  Yi-Chou Tsai*a  

* Corresponding authors

a Department of Chemistry, Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu, Taiwan
E-mail: yictsai@mx.nthu.edu.tw
Fax: +886 3 5711082
Tel: +886 3 5718232

b Department of Chemistry, National Taiwan Normal University, Taipei, Taiwan

c Department of Chemistry, National Taiwan University, Taipei, Taiwan

Abstract

Reactions of NO with the quintuple bonded chromium and molybdenum amidinate dimers, respectively, gave dichromium nitrosyl nitrito amidinato complexes, and the quadruple bonded dimolybdenum nitrito amidinato species with a paddlewheel configuration.

Graphical abstract: Divergent reactivity of nitric oxide with metal–metal quintuple bonds

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Article information

DOI
https://doi.org/10.1039/C3CC37118B
Article type
Communication
Submitted
30 Sep 2012
Accepted
08 Jan 2013
First published
09 Jan 2013

Chem. Commun., 2013,49, 4391-4393

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Divergent reactivity of nitric oxide with metal–metal quintuple bonds

P. Wu, S. Liu, Y. Shieh, T. Kuo, G. Lee, Y. Wang and Y. Tsai, Chem. Commun., 2013, 49, 4391 DOI: 10.1039/C3CC37118B

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