Issue 39, 2013
From the journal:

Chemical Communications

Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes†‡

Tetsuya Fukuda,a   Hisako Hashimoto*a  and  Hiromi Tobita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, Japan
E-mail: hhashimoto@m.tohoku.ac.jp, tobita@m.tohoku.ac.jp
Fax: +81 22 795 6543
Tel: +81 22 795 6540

Abstract

A germylyne complex Cp*(CO)2W[triple bond, length as m-dash]GeC(SiMe3)3 (1) reacted with alcohols to give simple nucleophilic addition products, while 1 reacted with two molecules of arylaldehydes consecutively to give base-stabilised alkoxy(germylene) complexes via C–H bond activation and hydrogermylation.

Graphical abstract: Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC37126J
Article type
Communication
Submitted
01 Oct 2012
Accepted
01 Nov 2012
First published
02 Nov 2012

Chem. Commun., 2013,49, 4232-4234

Permissions

Request permissions

Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

T. Fukuda, H. Hashimoto and H. Tobita, Chem. Commun., 2013, 49, 4232 DOI: 10.1039/C2CC37126J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements