Issue 4, 2013
From the journal:

Polymer Chemistry

Synthesis of 4-iodotetrahydropyran-containing polymersvia TMSI-promoted Prins cyclization

Shinsuke Inagi,*a   Naoko Takeia  and  Toshio Fuchigamia  

* Corresponding authors

a Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan
E-mail: inagi@echem.titech.ac.jp
Fax: +81-45-924-5407
Tel: +81-45-924-5407

Abstract

4-Iodotetrahydropyran (THP)-containing polymers were synthesized via Prins cyclization of monomers with an aldehyde moiety and a homoallylic alcohol moiety. The progress of polymerization was confirmed by NMR and GPC analysis. The deiodination of the THP in the polymer structure was carried out by reductive hydrogenation using AIBN and tributyltin hydride. Thermogravimetric analysis (TGA) was performed for the THP-containing polymers.

Graphical abstract: Synthesis of 4-iodotetrahydropyran-containing polymers via TMSI-promoted Prins cyclization

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Article information

DOI
https://doi.org/10.1039/C2PY20890C
Article type
Paper
Submitted
24 Oct 2012
Accepted
21 Nov 2012
First published
22 Nov 2012

Polym. Chem., 2013,4, 1221-1227

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Synthesis of 4-iodotetrahydropyran-containing polymers via TMSI-promoted Prins cyclization

S. Inagi, N. Takei and T. Fuchigami, Polym. Chem., 2013, 4, 1221 DOI: 10.1039/C2PY20890C

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