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The preparation of α,ω-hydroxy-telechelic poly(cyclohexene carbonate) from a dizinc catalyst is reported. The telechelic polymer, with an yttrium initiator, can be used to polymerize lactide, yielding new triblock copolymers, substantially derived from renewable resources.

Graphical abstract: Triblock copolymers from lactide and telechelic poly(cyclohexene carbonate)

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