Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake

Wen-Yang Gao; Youhong Niu; Yao Chen; Lukasz Wojtas; Jianfeng Cai; Yu-Sheng Chen; Shengqian Ma

doi:10.1039/C2CE25484K

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Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO₂ uptake†

Wen-Yang Gao,^a Youhong Niu,^a Yao Chen,^a Lukasz Wojtas,^a Jianfeng Cai,^a Yu-Sheng Chen^b and Shengqian Ma*^a

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* Corresponding authors

^a Department of Chemistry, University of South Florida, 4202 East Flower Avenue, Tampa, Florida, United States
E-mail: sqma@usf.edu
Fax: +1-813-974 3203
Tel: +1-813-974 5217

^b ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, IL, USA

Abstract

A two-fold interpenetrating microporous metal–organic framework, MMCF-1, has been constructed via the self-assembly of a custom-designed macrocyclic tetracarboxylate ligand and Cd(II), and it exhibits interesting selective uptake of CO₂ over N₂.

This article is part of the themed collection: New Talent: Americas

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Article information

DOI: https://doi.org/10.1039/C2CE25484K
Article type: Communication
Submitted: 02 Apr 2012
Accepted: 25 Apr 2012
First published: 26 Apr 2012

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CrystEngComm, 2012,14, 6115-6117

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Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO₂ uptake

W. Gao, Y. Niu, Y. Chen, L. Wojtas, J. Cai, Y. Chen and S. Ma, CrystEngComm, 2012, 14, 6115 DOI: 10.1039/C2CE25484K

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