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Nanostructured silicon hollow spheres with a thin shell have been synthesized by magnesium reduction of silica spheres, which possess a high BET surface area and are electrochemically active in capacitive energy storage with a maximum specific capacitance of 193 F g−1 in the neutral Na2SO4 aqueous solution.

Graphical abstract: Facile preparation of silicon hollow spheres and their use in electrochemical capacitive energy storage

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